Soldering

[Desoldering a contact from a wire.]

Soldering is a process in which two or more metal items are joined together by melting and flowing a filler metal (solder) into the joint, the filler metal having a lower melting point than the workpiece. Soldering differs from welding in that soldering does not involve melting the work pieces. In brazing, the filler metal melts at a higher temperature, but the workpiece metal does not melt. Formerly nearly all solders contained lead, but environmental concerns have increasingly dictated use of lead-free alloys for electronics and plumbing purposes.

Applications

Soldering is used in plumbing, in electronics and metalwork from flashing to jewelry.

Soldering provides reasonably permanent but reversible connections between copper pipes in plumbing systems as well as joints in sheet metal objects such as food cans, roof flashing, rain gutters and automobile radiators.

Jewelry components, machine tools and some refrigeration and plumbing components are often assembled and repaired by the higher temperature silver soldering process. Small mechanical parts are often soldered or brazed as well. Soldering is also used to join lead came and copper foil in stained glass work. It can also be used as a semi-permanent patch for a leak in a container or cooking vessel.

Electronic soldering connects electrical wiring and electronic components to printed circuit boards (PCBs).

Solders

Soldering filler materials are available in many different alloys for differing applications. In electronics assembly, the eutectic alloy of 63% tin and 37% lead (or 60/40, which is almost identical in melting point) has been the alloy of choice. Other alloys are used for plumbing, mechanical assembly, and other applications. Some examples of soft-solder are tin-lead for general purposes, tin-zinc for joining aluminium, lead-silver for strength at higher than room temperature, cadmium-silver for strength at high temperatures, zinc-aluminium for aluminium and corrosion resistance, and tin-silver and tin-bismuth for electronics.

A eutectic formulation has advantages when applied to soldering: the liquidus and solidus temperatures are the same, so there is no plastic phase, and it has the lowest possible melting point. Having the lowest possible melting point minimizes heat stress on electronic components during soldering. And, having no plastic phase allows for quicker wetting as the solder heats up, and quicker setup as the solder cools. A non-eutectic formulation must remain still as the temperature drops through the liquidus and solidus temperatures. Any movement during the plastic phase may result in cracks, resulting in an unreliable joint.

Common solder formulations based on tin and lead are listed below. The fraction represent percentage of tin first, then lead, totaling 100%:

63/37: melts at 183 °C (361 °F) (eutectic: the only mixture that melts at a point, instead of over a range)

60/40: melts between 183–190 °C (361–374 °F)

50/50: melts between 185–215 °C (365–419 °F)

For environmental reasons (and the introduction of regulations such as the European RoHS (Restriction of Hazardous Substances Directive)) lead-free solders are becoming more widely used. They are also suggested anywhere young children may come into contact with (since young children are likely to place things into their mouths), or for outdoor use where rain and other precipitation may wash the lead into the groundwater. Unfortunately, most lead-free solders are not eutectic formulations, melting at around 250 °C (482 °F), making it more difficult to create reliable joints with them.

Other common solders include low-temperature formulations (often containing bismuth), which are often used to join previously-soldered assemblies without un-soldering earlier connections, and high-temperature formulations (usually containing silver) which are used for high-temperature operation or for first assembly of items which must not become unsoldered during subsequent operations. Alloying silver with other metals changes the melting point, adhesion and wetting characteristics, and tensile strength. Of all the brazing alloys, silver solders have the greatest strength and the broadest applications. Specialty alloys are available with properties such as higher strength, better electrical conductivity, and higher corrosion resistance.

Processes

There are three forms of soldering, each requiring progressively higher temperatures and producing an increasingly stronger joint strength:

Soft soldering, which originally used a tin-lead alloy as the filler metal,

silver soldering, which uses an alloy containing silver,

brazing which uses a brass alloy for the filler.

The alloy of the filler metal for each type of soldering can be adjusted to modify the melting temperature of the filler. Soldering differs from gluing significantly in that the filler metals alloy with the workpiece at the junction to form a gas- and liquid-tight bond.

Soft soldering is characterized by having a melting point of the filler metal below approximately 400 °C (752 °F),whereas silver soldering and brazing use higher temperatures, typically requiring a flame or carbon arc torch to achieve the melting of the filler. Soft solder filler metals are typically alloys (often containing lead) that have liquidus temperatures below 350°C.

In this soldering process, heat is applied to the parts to be joined, causing the solder to melt and to bond to the workpieces in an alloying process called wetting. In stranded wire, the solder is drawn up into the wire by capillary action in a process called 'wicking'. Capillary action also takes place when the workpieces are very close together or touching. The joint strength is dependent on the filler metal used. Soldering produces electrically-conductive, water- and gas-tight joints.

Each type of solder offers advantages and disadvantages. Soft solder is so called because of the soft lead that is its primary ingredient. Soft soldering uses the lowest temperatures but does not make a strong joint and is unsuitable for mechanical load-bearing applications. It is also unsuitable for high-temperature applications as it softens and melts. Silver soldering, as used by jewelers, machinists and in some plumbing applications, requires the use of a torch or other high-temperature source, and is much stronger than soft soldering. Brazing provides the strongest joint but also requires the hottest temperatures to melt the filler metal, requiring a torch or other high temperature source and darkened goggles to protect the eyes from the bright light produced by the white-hot work. It is often used to repair cast-iron objects, wrought-iron furniture, etc.

Soldering operations can be performed with hand tools, one joint at a time, or en masse on a production line. Hand soldering is typically performed with a soldering iron, soldering gun, or a torch, or occasionally a hot-air pencil. Sheetmetal work was traditionally done with "soldering coppers" directly heated by a flame, with sufficient stored heat in the mass of the soldering copper to complete a joint; torches or electrically-heated soldering irons are more convenient. All soldered joints require the same elements of cleaning of the metal parts to be joined, fitting up the joint, heating the parts, applying flux, applying the filler, removing heat and holding the assembly still until the filler metal has completely solidified. Depending on the nature of flux material used, cleaning of the joints may be required after they have cooled.

Each alloy has characteristics that work best for certain applications, notably strength and conductivity, and each type of solder and alloy has different melting temperatures. The term silver solder likewise denotes the type of solder that is used. Some soft solders are "silver bearing" alloys used to solder silver-plated items. Lead based solders should not be used on precious metals because the lead dissolves the metal and disfigures it.

Brazing

[Brazing practice]

Brazing is a metal-joining process whereby a filler metal is heated above melting point and distributed between two or more close-fitting parts by capillary action. The filler metal is brought slightly above its melting (liquidus) temperature while protected by a suitable atmosphere, usually a flux. It then flows over the base metal (known as wetting) and is then cooled to join the workpieces together. It is similar to soldering, except the temperatures used to melt the filler metal are higher.

Fundamentals

In order to obtain high-quality brazed joints, parts must be closely fitted, and the base metals must be exceptionally clean and free of oxides. In most cases, joint clearances of 0.03 to 0.08 mm (0.0012 to 0.0031 in) are recommended for the best capillary action and joint strength. However, in some brazing operations it is not uncommon to have joint clearances around 0.6 mm (0.024 in). Cleanliness of the brazing surfaces is also important, as any contamination can cause poor wetting (flow). The two main methods for cleaning parts, prior to brazing are chemical cleaning, and abrasive or mechanical cleaning. In the case of mechanical cleaning, it is important to maintain the proper surface roughness as wetting on a rough surface occurs much more readily than on a smooth surface of the same geometry.

Another consideration that cannot be overlooked is the effect of temperature and time on the quality of brazed joints. As the temperature of the braze alloy is increased, the alloying and wetting action of the filler metal increases as well. In general, the brazing temperature selected must be above the melting point of the filler metal. However, there are several factors that influence the joint designer's temperature selection. The best temperature is usually selected so as to: (1) be the lowest possible braze temperature, (2) minimize any heat effects on the assembly, (3) keep filler metal/base metal interactions to a minimum, and (4) maximize the life of any fixtures or jigs used. In some cases, a higher temperature may be selected to allow for other factors in the design (e.g. to allow use of a different filler metal, or to control metallurgical effects, or to sufficiently remove surface contamination). The effect of time on the brazed joint primarily affects the extent to which the aforementioned effects are present; however, in general most production processes are selected to minimize brazing time and the associated costs. This is not always the case, however, since in some non-production settings, time and cost are secondary to other joint attributes (e.g. strength, appearance).